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Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ2 C 1,N]bis[2-(pyridin-2-yl)phenyl-κ2 C 1,N]iridium(III)
- Lee, Chiheon;
- Moon, Suk-hee;
- Park, Ki-min;
- Kang, Youngjin
Citations
SCOPUS
1초록
In the title compound, [Ir(C11H8N)2(C18H14N)], the IrIII ion adopts a distorted octahedral coordination environment defined by three C,N-chelating ligands, one stemming from a 2-(4-phenyl-5-methylpyridin-2-yl)phenyl ligand and two from 2-(pyridin-2-yl)phenyl ligands, arranged in a facial manner. The IrIII ion lies almost in the equatorial plane [deviation = 0.0069(15)Å]. In the crystal, intermolecular π-π stacking interactions, as well as intermolecular C - H⋯π interactions, are present, leading to a three-dimensional network.
키워드
C,N-bidentate ligand; crystal structure; fac-C3N3 coordination set; iridium(III) complex; π-π stacking interactions
- 제목
- Crystal structure of fac-[2-(4-methyl-5-phenylpyridin-2-yl)phenyl-κ2 C 1,N]bis[2-(pyridin-2-yl)phenyl-κ2 C 1,N]iridium(III)
- 저자
- Lee, Chiheon; Moon, Suk-hee; Park, Ki-min; Kang, Youngjin
- 발행일
- 2016
- 유형
- Article
- 권
- 72
- 페이지
- 1768 ~ 1770