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Anion-controlled assemblies from pseudo-cyclic cadmium(II) complex and spacer coligand
- Park, Ki-Min;
- Moon, Seok-Tae;
- Kang, Young Jin;
- Kim, Hyun Jee;
- Seo, Joobeom;
- 외 1명
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22초록
Self-assembly of the dipodal ligand L and CdX2 (X = ClO4 and NO3) produced unique pseudo-cyclic complexes (A) [Cd(L)(H2O)(CH3OH)](ClO4)(2) (1) and [Cd(L)(H2O)(NO3)](NO3) (2), respectively. From the stepwise reaction of the pseudo-cyclic complexes (A) followed by coligands (B) such as 4,4'-bipyridine and terephthalate, the controlled one-dimensional coordination polymer {[Cd(L)(H2O)(bpy))(ClO4)(2)(MeOH)(0.5)}(n) (3) with (A-B)(n) array and the discrete "dumbbell"-like complex [Cd-2(L)(2)(tp)(H2O)(2)](tp)(H2O)(9) (4) with (A-B-A) patterns were isolated. (C) 2006 Elsevier B.V. All rights reserved.
키워드
dipodal ligand; cadmium(II) complex; pseudo cyclic complex; 1-D coordination polymer; dumbbell-like complex; COORDINATION POLYMERS; CHEMISTRY; DESIGN; DERIVATIVES; NETWORKS
- 제목
- Anion-controlled assemblies from pseudo-cyclic cadmium(II) complex and spacer coligand
- 저자
- Park, Ki-Min; Moon, Seok-Tae; Kang, Young Jin; Kim, Hyun Jee; Seo, Joobeom; Lee, Shim Sung
- 발행일
- 2006-07
- 유형
- Article
- 권
- 9
- 호
- 7
- 페이지
- 671 ~ 674