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초록
Pd-Catalyzed carbon-sulfur cross-coupling reactions of aryl chlorides with indium tris(organothiolates) were developed. Aryl chlorides reacted with indium tris(organothiolates) (0.35 equiv) in the presence of 4 mol % of Pd(OAc)(2), 4.2 mol % of Xantphos, and Cs2CO3 as an additive, producing aryl-aryl and aryl-alkyl sulfides in good to excellent yields.
키워드
S BOND FORMATION; HIGHLY EFFICIENT; ONE-POT; LIGAND; IODIDES; HALIDES; THIOLS; BROMIDES; THIOETHERS; ARYLATION
- 제목
- Palladium-catalyzed Carbon-Sulfur Cross-coupling Reactions of Aryl Chlorides with Indium Tris(organothiolates)
- 저자
- Mo, Juntae; Eom, Dahan; Kim, Sung Hong; Lee, Phil Ho
- 발행일
- 2011-09-05
- 유형
- Article
- 권
- 40
- 호
- 9
- 페이지
- 980 ~ 982