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An olefin disconnection strategy for the practical synthesis of (+)-brefeldin A: olefin cross metathesis and intramolecular Horner-Wadsworth-Emmons olefination
- Seo, Seung-Yong;
- Jung, Jae-Kyung;
- Paek, Seung-Mann;
- Lee, Yong-Sil;
- Kim, Seok-Ho;
- 외 1명
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21초록
The practical and convergent total synthesis of (+)-brefeldin A has been achieved by an olefin disconnection strategy. Key features of the total synthesis include the efficient formation of C2 and C10 olefins, employing an olefin cross metathesis (CM) reaction and an intramolecular HWE olefination, respectively. (c) 2006 Elsevier Ltd. All rights reserved.
키워드
BREFELDIN-A; CYCLOADDITIONS
- 제목
- An olefin disconnection strategy for the practical synthesis of (+)-brefeldin A: olefin cross metathesis and intramolecular Horner-Wadsworth-Emmons olefination
- 저자
- Seo, Seung-Yong; Jung, Jae-Kyung; Paek, Seung-Mann; Lee, Yong-Sil; Kim, Seok-Ho; Suh, Young-Ger
- 발행일
- 2006-09-11
- 유형
- Article
- 권
- 47
- 호
- 37
- 페이지
- 6527 ~ 6530