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An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest
- Park, Ki-Min;
- Lee, Sanjina;
- Kang, Youngjin;
- Moon, Suk-Hee;
- Lee, Shim Sung
Citations
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12Citations
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12초록
From the reaction of (CuCN)-C-I with conc-NH4OH, a host-guest type 3D network complex 1, {[Cu-II(NH3)(4)(H2O)](H2O)@ [Cu-3(I)(CN)(5)]}(n) was isolated and characterised. A unique cationic complex guest [Cu-II(NH3)(4)(H2O)](2+) is encapsulated in the anionic host cage [Cu-3(I)(CN)(5)](2-).
키워드
MOLECULAR ARCHITECTURES; COORDINATION NETWORKS; CRYSTAL-STRUCTURE; HOST; CYANOCUPRATE(I); INCLUSION; CHEMISTRY; POLYMER; SYSTEMS; DESIGN
- 제목
- An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest
- 저자
- Park, Ki-Min; Lee, Sanjina; Kang, Youngjin; Moon, Suk-Hee; Lee, Shim Sung
- DOI
- 10.1039/b814646b
- 발행일
- 2008
- 유형
- Article
- 호
- 46
- 페이지
- 6521 ~ 6523
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 3 페이지
- ISSN
- E 1477-9234
P 1477-9226