An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest

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초록

From the reaction of (CuCN)-C-I with conc-NH4OH, a host-guest type 3D network complex 1, {[Cu-II(NH3)(4)(H2O)](H2O)@ [Cu-3(I)(CN)(5)]}(n) was isolated and characterised. A unique cationic complex guest [Cu-II(NH3)(4)(H2O)](2+) is encapsulated in the anionic host cage [Cu-3(I)(CN)(5)](2-).

키워드

MOLECULAR ARCHITECTURESCOORDINATION NETWORKSCRYSTAL-STRUCTUREHOSTCYANOCUPRATE(I)INCLUSIONCHEMISTRYPOLYMERSYSTEMSDESIGN
제목
An unusual anionic copper(I) cyanide 3D framework encapsulating a cationic copper(II) complex as a guest
저자
Park, Ki-MinLee, SanjinaKang, YoungjinMoon, Suk-HeeLee, Shim Sung
DOI
10.1039/b814646b
발행일
2008
유형
Article
저널명
Dalton Transactions
46
페이지
6521 ~ 6523