Ultrafast synthesis of gold nanoparticles on cellulose nanocrystals via microwave irradiation and their dyes-degradation catalytic activity

초록

This study represents a well-dispersed gold nanoparticles (AuNPs) synthesis process via cellulose nanocrystals (CNC) which acts as both reducing and supporting agent. The synthesis process was ultrafast and completed in a few seconds using microwave irradiation. The entire synthesis process was cost-effective, sustainable and eco-friendly. The synthesized (AuNPs/CNC) nanocomposite was investigated by transmission electron microscopy, selected area electron diffraction, Fourier transform infrared spectroscopy, energy dispersive X-ray analysis, X-ray diffraction, and UV-vis spectroscopy. The obtained AuNPs were well accumulated on the CNC surface and had a uniform spherical shape with an average diameter of 8 +/- 5.3 nm. The diameter of AuNPs could be altered by tuning the concentration of CNC suspension. The synthesized AuNPs/CNC nanocomposite film exhibited excellent degradation properties against various organic dyes, namely, Allura red, Congo red, Rhodamine B and Amaranth. The ultrafast degradation reactions followed pseudo first order kinetics. In the catalytic degradation reaction, AuNPs/CNC was transmitting electrons from a donor (NaBH4) to an acceptor (a dye). (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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