General trends of atmospheric mercury concentrations in urban and rural areas in Korea and characteristics of high-concentration events

초록

Long-term measurement of speciated Hg concentrations is the first step toward identifying the seasonal and spatial characteristics of Hg concentrations; however, atmospheric Hg research is scarce in Korea. In this study, total gaseous mercury (TGM), gaseous oxidized mercury (GUM) and particle-bound mercury (PBM) were measured in urban (Seoul) and rural (Chuncheon) areas over a more than 3 year period in order to improve the understanding of speciated Hg transport. The mean concentrations of TGM, GUM and PBM were 3.72 +/- 2.96 (0.19-149.84) ng m(-3),11.3 +/- 9.5 (0.9-57.3) pg m(-3), and 13.4 +/- 12.0 (2.1-64.3) pg m(-3) at the Seoul site and 2.12 +/- 1.47 (0.26-10.75) ng m(-3), 2.7 +/- 2.7 (0.1-16.9) pg m(-3), and 3.7 +/- 5.7 (0.1-30.0) pg m(-3) in Chuncheon. Both long-range transport and local sources caused high TGM concentration events, while local coal combustion was a main cause of enhancing the GUM and PBM concentrations in Seoul. However, there was no correlation between the pollutants emitted from coal combustion and the speciated Hg concentration in Chuncheon, indicating that other mechanisms were involved in the Hg increase. We found a positive correlation between the GUM and the O-3 concentrations and a negative correlation between the GEM and the GUM concentrations, especially on foggy days, suggesting that the oxidation of GEM was an important source for GUM in Chuncheon. In addition, the ratio of PBM/GOM was inversely proportional to the atmospheric temperature and directly proportional to the relative humidity, which suggests that the in-situ formation of PBM through gas-particle partitioning of GUM was important in rural areas. (C) 2014 Elsevier Ltd. All rights reserved.

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