Nanostructured sponge-like Au for selective electrochemical reduction of carbon dioxide

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초록

Gold nanoporous sponge structure is fabricated using a facile and one-step electrochemical technique without hazardous acids or bases for electrochemical reduction of CO2 to CO. The nanoporous Au shows highly selective conversion behavior for CO2 to CO. And, the CO faradaic current density on the basis of geometric area and electrochemical surface area of the nanoporous structured Au is significantly improved than the Au film, which is mainly due to highly and increased active sites at the catalytic surface. (C) 2018 Elsevier B.V. All rights reserved.

키워드

CO; CO2; Gold; Nanoporous structure; Low coordination sites; ELECTROCATALYTIC CO2 REDUCTION; PHOTOCATALYTIC REDUCTION; SURFACE-AREA; NANOPARTICLES; COPPER; ELECTROREDUCTION; ELECTRODES; HYDROCARBONS; NANOWIRES; INSIGHTS
제목
Nanostructured sponge-like Au for selective electrochemical reduction of carbon dioxide
저자
Kim, Jun-Hyuk; Youn, Duck Hyun
DOI
10.1016/j.cplett.2018.05.039
발행일
2018-07-16
유형
Article
저널명
Chemical Physics Letters
권
704
페이지
27 ~ 30