Gold-catalyzed 5-exo-dig and 6-exo-dig selective cyclizations of alkynyl silyl enol ethers:: Efficient method for [3+2] and [4+2] annulations onto α,β-enones

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WEB OF SCIENCE

39
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SCOPUS

43

초록

An efficient method for the annulation of five- and six-membered rings onto alpha,beta-enones is described via gold-catalyzed 5- and 6-exo-dig selective cyclizations of alkynyl silyl enol ethers.

키워드

[3+2] annulation; [4+2] annulation; catalysis; cyclization; gold; INTERNAL UNACTIVATED ALKYNES; ALPHA,BETA-UNSATURATED KETONES; FUNCTIONALIZED CYCLOPENTENES; (TRIMETHYLSILYL)CYCLOPENTENE ANNULATION; 5-MEMBERED RINGS; CYCLOPENTANNULATION; ENONES; CYCLOADDITION; GOLD(III)
제목
Gold-catalyzed 5-exo-dig and 6-exo-dig selective cyclizations of alkynyl silyl enol ethers:: Efficient method for [3+2] and [4+2] annulations onto α,β-enones
저자
Lee, Kooyeon; Lee, Phil Ho
DOI
10.1002/adsc.200700304
발행일
2007-09
유형
Article
저널명
Journal für Praktische Chemie
권
349
호
13
페이지
2092 ~ 2096