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초록
Tandem Diels-Alder/cross-coupling reactions with organoindium reagents generated in situ from 1-bromo-2,3-butadiene and indium were developed in a one-pot process. [4 + 2] Cycloaddition reactions using organoindium reagents and subsequent Pd-catalyzed cross-coupling reactions provided the rapid synthesis of six-membered carbocycles starting from 1-bromo-2,3-butadiene.
키워드
INDIUM-MEDIATED 1,3-BUTADIEN-2-YLATION; CYCLOADDITION REACTIONS; CARBONYL-COMPOUNDS; ORGANIC-SYNTHESIS; ALDER REACTIONS; ALLYL ACETATES; ROUTE; DERIVATIVES; 1,3-DIENES; CHEMISTRY
- 제목
- Tandem Diels-Alder/Cross-Coupling Reactions of Generated in Situ Organoindium Reagents in a One-Pot Process
- 저자
- Mo, Juntae; Kim, Sung Hong; Lee, Phil Ho
- 발행일
- 2010-02-05
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 12
- 호
- 3
- 페이지
- 424 ~ 427