Efficient synthetic method of multisubstituted allenes from the reactions of allylindium reagents with 3°-propargyl alcohols

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초록

An efficient synthetic method of tri- and tetra-substituted allenes having an allyl and methallyl group was developed by the reactions of allylindium reagents generated in situ from indium and allyl bromides with 3 degrees-propargyl alcohols.

키워드

PALLADIUM-CATALYZED SYNTHESIS; CHIRAL AMINO ALLENES; STEREOSELECTIVE-SYNTHESIS; COUPLING REACTION; PROPARGYLIC ETHERS; CYCLIZATION; HALIDES; 1,2-DIENES
제목
Efficient synthetic method of multisubstituted allenes from the reactions of allylindium reagents with 3°-propargyl alcohols
저자
Lee, Kooyeon; Lee, Phil Ho
DOI
10.1021/ol800719g
발행일
2008-06-19
유형
Article
저널명
Organic Letters
권
10
호
12
페이지
2441 ~ 2444