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초록
The metal-free oxidation of organic compounds is one of the most demanding reactions in chemical industries. As such, iodoxybenzoic acid (IBX) is an attractive reagent due to its metal-free oxidative activity. To apply IBX for the alcohol oxidation in water, IBX was immobilized on graphene oxide (GO). GO-supported IBX reagent exhibited excellent performance for alcohol oxidation reaction in water with greater than 90% selectivity. It could be reused without significant loss of oxidative activity.
키워드
graphene oxide; iodoxybenzoic acid; alcohol oxidation; water-based system; AEROBIC OXIDATION; PALLADIUM NANOPARTICLES; SELECTIVE OXIDATION; GRAPHITE OXIDE; IBX; EFFICIENT; CATALYST; REAGENTS; CARBON; ENONES
- 제목
- Heterogeneous Transition-Metal-Free Alcohol Oxidation by Graphene Oxide Supported Iodoxybenzoic Acid in Water
- 저자
- Kim, Yo-Han; Jang, Hyung-Seok; Kim, Young-O; Ahn, So-Dam; Yeo, Sewon; Lee, Sang-Myung; Lee, Yoon-Sik
- 발행일
- 2013-10-22
- 유형
- Article
- 저널명
- Synlett
- 권
- 24
- 호
- 17
- 페이지
- 2282 ~ 2286